Fawcett Acidity and Basicity

The acidity (A_p) and basicity (B_p) values of Fawcett are obtained from the solvation energy of monoatomic ions interpreted using the mean spherical approximation.

See Blum and Fawcett; J.Phys.Chem. 96 (1992) 408.

Fawcett's A_p and B_p values
Name	CAS nr	A_p	B_p
2-propanone	67-64-1	22	12.55
4-methyl-2-oxo-1,3-dioxolane	108-32-7	23.9	11.4
acetonitrile	75-05-8	24.4	11.47
benzonitrile	100-47-0	23.3	11.2
butanol	71-36-3	34.5	11.3
dimethyl sulfoxide	67-68-5	25.6	13.3
ethanol	64-17-5	37.2	11.9
formamide	75-12-7	34.1	12.5
hexamethylphosphoramide	680-31-9	19.2	13.8
methanol	67-56-1	41	12.1
N,N-dimethylacetamide	127-19-5	20.1	13.5
N,N-dimethylformamide	68-12-2	22.2	13.2
N-methylformamide	123-39-7	31.5	12.6
N-methylpyrrolidone	872-50-4	22.1	14
nitrobenzene	98-95-3	26.4	10.6
nitromethane	75-52-5	25.5	10.7
propanol	71-23-8	34.7	12.05
sulfolane	126-33-0	22	12.5
water	7732-18-5	48	12.1

Tables for Chemistry

Fawcett Acidity and Basicity